{"id":1656,"date":"2026-03-10T16:28:02","date_gmt":"2026-03-10T19:28:02","guid":{"rendered":"https:\/\/cormanich.iqm.unicamp.br\/?p=1656"},"modified":"2026-03-10T16:28:02","modified_gmt":"2026-03-10T19:28:02","slug":"new-paper-in-pccp-4","status":"publish","type":"post","link":"https:\/\/cormanich.iqm.unicamp.br\/?p=1656","title":{"rendered":"New paper in PCCP"},"content":{"rendered":"\n<p class=\"wp-block-paragraph\">We are pleased to share our new publication in Physical Chemistry Chemical Physics titled <em>\u201cPerlin- and Bohlmann-type effects in cyclohexylamine and 1-aminopiperidine derivatives.\u201d<\/em><\/p>\n\n\n\n<p class=\"wp-block-paragraph\">In this work, we investigate how classical stereoelectronic effects, namely the <strong>Perlin<\/strong> and <strong>Bohlmann<\/strong> effects, manifest in cyclohexylamine and 1-aminopiperidine derivatives. By analyzing spectroscopic data, we explore the electronic interactions responsible for these phenomena and their relationship with molecular conformation.<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">Our results indicate that the Bohlmann-type effect observed in N\u2013H stretching vibrations is mainly associated with hyperconjugative interactions, whereas the Perlin effect observed in 1JCH coupling constants is largely driven by steric (Lewis-type) interactions, with hyperconjugation playing a secondary role in modulating the magnitude of the effect.<\/p>\n\n\n\n<p class=\"wp-block-paragraph\"><\/p>\n","protected":false},"excerpt":{"rendered":"<p>We are pleased to share our new publication in Physical Chemistry Chemical Physics titled \u201cPerlin- and Bohlmann-type effects in cyclohexylamine and 1-aminopiperidine derivatives.\u201d In this work, we investigate how classical stereoelectronic effects, namely the Perlin and Bohlmann effects, manifest in cyclohexylamine and 1-aminopiperidine derivatives. By analyzing spectroscopic data, we explore the electronic interactions responsible for&#8230;<\/p>\n","protected":false},"author":1,"featured_media":1657,"comment_status":"closed","ping_status":"","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[4],"tags":[],"class_list":["post-1656","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-post"],"_links":{"self":[{"href":"https:\/\/cormanich.iqm.unicamp.br\/index.php?rest_route=\/wp\/v2\/posts\/1656","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/cormanich.iqm.unicamp.br\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/cormanich.iqm.unicamp.br\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/cormanich.iqm.unicamp.br\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/cormanich.iqm.unicamp.br\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=1656"}],"version-history":[{"count":1,"href":"https:\/\/cormanich.iqm.unicamp.br\/index.php?rest_route=\/wp\/v2\/posts\/1656\/revisions"}],"predecessor-version":[{"id":1658,"href":"https:\/\/cormanich.iqm.unicamp.br\/index.php?rest_route=\/wp\/v2\/posts\/1656\/revisions\/1658"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/cormanich.iqm.unicamp.br\/index.php?rest_route=\/wp\/v2\/media\/1657"}],"wp:attachment":[{"href":"https:\/\/cormanich.iqm.unicamp.br\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=1656"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/cormanich.iqm.unicamp.br\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=1656"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/cormanich.iqm.unicamp.br\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=1656"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}